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for the TRIGA research reactors. The resulting very large negative temperature coef cient of reactivity provides a large safety margin for reactor operation. Uranium halides exist in the 3 oxidation state (UF3, UCl3, UBR3, UI3), the 4 oxidation state (UF4, UCl4, UBr4, and UI4), the 5 oxidation state (UF5, UCl5), and the 6 oxidation state (UF6, UCl6). UF4 ( green salt ) is an intermediate in the production of U and UF6. It can be made by reacting UO2 with excess HF as ) UO2 4HF ( UF4 2H2 O or, for laboratory use, by the reaction ! U4 4F UF4 # (Uranium tetra uoride precipitated from aqueous solutions exists as UF4 . 5H2O, and it is dif cult to remove the waters of hydration so that the dry reaction above is preferred.) UF4 is frequently used to make accelerator targets of uranium by vacuum volatilization. UF6 ( hex ) is the only readily available uranium compound that is volatile at room temperature. It is a colorless solid that is used in the uranium enrichment process. It sublimes at room temperature without melting. UF6 is rapidly hydrolyzed by water and is a uorinating agent. This latter property means that one must carefully choose the materials to contain UF6. 16.3.4 Uranium Solution Chemistry The solution chemistry of uranium is that of the 4 and 6 oxidation states, that is, U4 and UO2 . The formal reduction potential of uranium in aqueous solution (i.e., 2 1 M HClO4) is asp.net code 128 reader C# Code 128 Reader SDK to read, scan Code 128 in C#.NET class ...
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